No, there is only a setting to alert when an connection is incoming.i read that there is specific policy could be adjusted to make windows firewall pop notification about any program try to connect the internet.
+1, people relies too much on 3rd party software instead of learning the basics of tools shipped with their OS.you do not need to use TinyWall to have good firewall protection nor a front end like WFC to control Windows Firewall Control
in fact, programs like that are crutches that you come to depend upon to do stuff you should figure out and learn this stuff on your own
such programs keep you in ignorance
i mentioned it in another thread long time ago.i exported policy (.WFW) after being created by Tinywall not the exported rules from Tinywall itself
1- install Binisoft WFC.
2- clear the Windows Firewall rules.
3- install WFC default rules.
4- launch every of your internet-facing apps, allow them; do some reboot (or keep WFC for few days) to be sure some services/processes are triggered.
5- export the .wfw policy.
6- remove WFC.
job done, you have most of the basic rules now. And if you like "default-deny" firewall setup, block all outbound connection in WinFW w/Advanced settings.